Extreme ultraviolet photolysis of CO2- H2O mixed ices at 10 K
نویسندگان
چکیده
منابع مشابه
Surface abundance change in vacuum ultraviolet photodissociation of CO2 and H2O mixture ices.
Photodissociation of amorphous ice films of carbon dioxide and water co-adsorbed at 90 K was carried out at 157 nm using oxygen-16 and -18 isotopomers with a time-of-flight photofragment mass spectrometer. O((3)P(J)) atoms, OH (v = 0) radicals, and CO (v = 0,1) molecules were detected as photofragments. CO is produced directly from the photodissociation of CO(2). Two different adsorption states...
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Context. H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 μm stretching, the 6 μm bending intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect the positions, shapes and relative strengths of the 3 μ...
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Fourier transform infrared (FTIR) spectroscopy combined with a long-path collisional cooling cell was used to investigate the temporal evolution of CO2 nanoparticles and binary H2O/CO2 nanocomposites in the aerosol phase at 80 K. The experimental conditions for the formation of different CO2 particle shapes as slab, shell, sphere, cube, and needle have been studied by comparison with calculated...
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The detection of nucleobases in carbonaceous chondrites such as Murchison supports the scenario in which extraterrestrial organic molecules could have contributed to the origin of life on Earth. However, such large molecules have not been observed to date in astrophysical environments, in particular, comets and the interstellar medium (ISM). The physico-chemical conditions under which nucleobas...
متن کاملPhotodesorption of Ices Ii: H2o and D2o
Gaseous H2O has been detected in several cold astrophysical environments, where the observed abundances cannot be explained by thermal desorption of H2O ice or by H2O gas phase formation. These observations hence suggest an efficient non-thermal ice desorption mechanism. Here, we present experimentally determined UV photodesorption yields of H2O and D2O ice and deduce their photodesorption mech...
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ژورنال
عنوان ژورنال: Journal of Geophysical Research
سال: 2003
ISSN: 0148-0227
DOI: 10.1029/2002je001932